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CAS Number: 100516-54-9
(2R,3S)-benzyl 6-oxo-2,3-diphenylmorpholine-4-carboxylate

Structure

(2R,3S)-benzyl 6-oxo-2,3-diphenylmorpholine-4-carboxylate
Name: (2R,3S)-benzyl 6-oxo-2,3-diphenylmorpholine-4-carboxylate
Synonyms:
General Information
Product Number: 100516549
CAS Number:
100516-54-9
Name:
4-Morpholinecarboxylicacid, 6-oxo-2,3-diphenyl-, phenylmethyl ester, (2R,3S)-
Formula:
C24H21NO4.
Molecular Weight:
387.43
Synonyms:
4-Morpholinecarboxylicacid, 6-oxo-2,3-diphenyl-, phenylmethyl ester, (2R-cis)-;William's lactone;
InChI: InChI=1S/C24H21NO4/c26-21-16-25(24(27)28-17-18-10-4-1-5-11-18)22(19-12-
6-2-7-13-19)23(29-21)20-14-8-3-9-15-20/h1-15,22-23H,16-17H2/t22-,
23+/m0/s1
InChIKey: HECRUWTZAMPQOS-XZOQPEGZSA-N
Canonical SMILES : C1C(=O)OC(C(N1C(=O)OCC2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4
Deleted CAS Registry Numbers: 167549-69-1
 
Optical and Scattering Properties Value Condition Note
Optical Rotatory Power -67.4 ° Conc: 5.50 g/100mL; Solv: dichloromethane (75-09-2); Temp: 25 °C (1)IC
Optical Rotatory Power -68.7 ° Conc: 1.0 g/100mL; Solv: dichloromethane (75-09-2); Wavlen: 589.3 nm; Temp: 22 °C (2)CAS

Thermal Properties Value Condition Note
Melting Point 209-210 °C Solv: ethanol (64-17-5) (1)IC
Melting Point 206-207 °C   (2)CAS

 

Specification

98%

References

 

  1. (1) Williams, Robert M.; Journal of the American Chemical Society 1988, V110(5), P1547-57 CAPLUS
  2. (2) Dastlik, Kim A.; Synlett 2005, (4), P693-696 CAPLUS
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